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The Stark-Einstein law of the law of photochemical equivalence applies to the light-inducing reaction’s part which is also termed ad primary process which is the starting chemical change resulting in the absorption of light. Usually, in the photochemical reactions, the primary process is carried forward by the secondary processes which is about the reactants and their interactions that do not need the absorption of light. And, the result of this is that these reactions do not comply with the quantum one-molecule reactant relation. Also, this photochemical equivalence law is limited to the traditional photochemical reactions, the reactions that involve high intensities of light sources like the ones of laser and flash photolysis results in the bi-photonic process which is when the molecules of any given substance absorb two photons of light. This law was given the name of Stark-Einstein after the physicists who were born in Germany, Albert Einstein and Johannes Stark.
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The Jablonski diagram which is given in the picture below is of the photoluminescent molecule’s energy in various states and it is a partial energy diagram. The electronic energy of the ground state of the molecule which is in the singlet state S0 is represented by the lowest horizontal and dark line. An, majorly all the molecules are in this state at the room temperature. The line above it are for the three excited electronic state in which T1 represents the electronic triplet state and S1 and S2 represents the electronic singlet state.
The Stark-Einstein law is the one which is known as the second law of photochemistry states that only one molecule come sin the active state for a secondary reaction when even a single photon of light is being absorbed by the chemical substance. During the developments of the quantum theory of light, Albert Einstien derived this photoequivalence law.
For the study of all chemical processes that are the result of the absorption of light, photochemistry is used. For the advancement of sustainable sources of energy, studying photochemical systems that use sunlight to carry forward some important chemical reactions, is of great significance.
Molecules that are originally not photoactive, when induced with photochemical reactions by an excited molecule in a reaction is called photosensitized reaction. This is done on the molecules that do not absorb light in the range of considered wavelength.
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